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Dissertation
Biodegradable polymers and the optimalisation of their temperature resistance
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Year: 2013 Publisher: Gent : s.n.,

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Because of the rising prices and depletion of crude oil and the rising environmental awareness, biodegradable and biobased polymers get increasing attention and become an alternative to synthetic polymers. The properties of polymers such as polylactide (PLA) and polyhydroxybutyrate (PHB) need to be, however, still further optimized. Certainly the thermal stability of these polymers needs to be strong enhanced. The purpose of this study is to investigate the mechanical and thermal properties of these polymers, and the thermal degradation.In this study, various biodegradable polymers are processed in an injection molding machine. It is a PLA, a high-heat PLA and a PLA with a natural fiber. PP is also produced to compare the biodegradable polymers with this widely used material because they will have to compete with PP. The mechanical properties of these polymers can be investigated and compared by performing tensile tests, flexural tests, and heated tensile tests. The thermal properties such as glass transition temperature (Tg) and the melting temperature (Tm) and the crystallinity are investigated by means of DSC analysis. In addition to the above-mentioned biodegradable polymers, a PHB and a PHB-PLA blend are also investigated by means of DSC analysis. The thermal degradation of the PLA and the high-heat PLA is examined by injecting several series with increasing residence time in the screw. MFI measurements then were done on this series. The high-heat PLA and the PLA with natural fiber have the highest modulus and are more brittle than the other materials. The neat PLA can, however, followed by the PLA with natural fiber and the high-heat PLA, take on the highest load. The DSC analysis shows that the high-heat PLA and the PLA with natural fiber have the highest Tm. The MFI measurements show that the thermal degradation occurs when the residence time in the screw is increased. The neat PLA degrades faster than the high-heat PLA. Door de stijgende prijzen en uitputting van ruwe aardolie en de stijgende milieubewustheid krijgen biodegradeerbare en biogebaseerde polymeren steeds meer aandacht en vormen een alternatief voor synthetische polymeren. De eigenschappen van polymeren zoals bijvoorbeeld polylactide (PLA) en polyhydroxybutyraat (PHB) moeten echter nog verder geoptimaliseerd worden. Zeker de thermische stabiliteit van deze polymeren is nog aan sterke verbeteringen toe. Het doel van dit onderzoek is het onderzoeken van de mechanische en thermische eigenschappen van deze polymeren en de thermische degradatie.In dit onderzoek worden verschillende biodegradeerbare polymeren verwerkt in een spuitgietmachine. Het betreft een PLA, een high-heat PLA en een PLA met een natuurlijke vezel. Ook worden er spuitstukken van PP geproduceerd om de biodegradeerbare polymeren te kunnen vergelijken met dit veelgebruikte materiaal. De biodegradeerbare polymeren zullen namelijk moeten concurreren met dit materiaal. De mechanische eigenschappen van deze polymeren worden onderzocht en vergeleken door het uitvoeren van trekproeven, buigproeven en verwarmde trekproeven. De thermische eigenschappen zoals glastransitietemperatuur (Tg) en de smelttemperatuur (Tm) en de kristalliniteit worden onderzocht via DSC-analyse. Naast bovenvermelde biodegradeerbare polymeren wordt ook een PHB en een PHB-PLA blend onderzocht via DSC-analyse. De thermische degradatie van het PLA en het high-heat PLA wordt nagegaan door verschillende reeksen te spuiten met oplopende verblijftijd in de schroef en hierop MFI-metingen uit te voeren. De high-heat PLA en de PLA met natuurlijke vezel hebben de hoogste modulus en zijn brosser dan de andere materialen. Het nette PLA kan echter de hoogste belasting dragen gevolgd door het PLA met natuurlijke vezel en de high-heat PLA. De DSC-analyse toont aan dat de high-heat PLA en de PLA met natuurlijke vezel de hoogste Tm hebben. Uit de MFI-metingen blijkt dat thermische degradatie o ptreedt wanneer de verblijftijd in de schroef wordt verhoogd. Het nette PLA degradeert sneller dan het high-heat PLA.


Book
Performance and Application of Novel Biocomposites
Author:
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Amidst impending climate change and enhanced pollution levels around the globe, the need of the hour is to develop bio-based materials that are sustainable and possess comparable performance properties to their synthetic counterparts. In light of the aforementioned, numerous investigations are being conducted to identify, process, and create materials that are concurrently innocuous towards the environment and have superior properties. This book is a collection of such scientific articles that propagate novel ideas for the development of polymeric composite materials, which have application potential in numerous fields such as medicine, automobile, aviation, construction, etc. It also contains a pedagogical article that proposes some strategies to continue experimental research during pandemics. This book will provide readers a quick glance into recent developments regarding polymeric materials and will encourage them to propagate these research ideas further.


Book
Bio-Based and Biodegradable Plastics : From Passive Barrier to Active Packaging Behavior
Authors: --- ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Over the few coming decades, bio-based and biodegradable plastics produced from sustainable bioresources should essentially substitute the prevalent synthetic plastics produced from exhaustible hydrocarbon fossils. To the greatest extend, this innovative trend has to apply to the packaging manufacturing area and especially to food packaging implementation. To supply the rapid production increment of biodegradable plastics, there must be provided the effective development of scientific-technical potential that promotes the comprehensive exploration of their structural, functional, and dynamic characteristics. In this regard, the transition from passive barrier materials preventing water and oxygen transport as well as bacteria infiltration to active functional packaging that ensures gas diffusion selectivity, antiseptics' and other modifiers' release should be based on the thorough study of biopolymer crystallinity, morphology, diffusivity, controlled biodegradability and life cycle assessment. This Special Issue accumulates the papers of international teams that devoted to scientific and industrial bases providing the biodegradable material development in the barrier and active packaging as well as in agricultural applications. We hope that book will bring great interest to the experts in the area of sustainable biopolymers.


Book
Bio-Based and Biodegradable Plastics : From Passive Barrier to Active Packaging Behavior
Authors: --- ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Over the few coming decades, bio-based and biodegradable plastics produced from sustainable bioresources should essentially substitute the prevalent synthetic plastics produced from exhaustible hydrocarbon fossils. To the greatest extend, this innovative trend has to apply to the packaging manufacturing area and especially to food packaging implementation. To supply the rapid production increment of biodegradable plastics, there must be provided the effective development of scientific-technical potential that promotes the comprehensive exploration of their structural, functional, and dynamic characteristics. In this regard, the transition from passive barrier materials preventing water and oxygen transport as well as bacteria infiltration to active functional packaging that ensures gas diffusion selectivity, antiseptics' and other modifiers' release should be based on the thorough study of biopolymer crystallinity, morphology, diffusivity, controlled biodegradability and life cycle assessment. This Special Issue accumulates the papers of international teams that devoted to scientific and industrial bases providing the biodegradable material development in the barrier and active packaging as well as in agricultural applications. We hope that book will bring great interest to the experts in the area of sustainable biopolymers.


Book
Performance and Application of Novel Biocomposites
Author:
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Amidst impending climate change and enhanced pollution levels around the globe, the need of the hour is to develop bio-based materials that are sustainable and possess comparable performance properties to their synthetic counterparts. In light of the aforementioned, numerous investigations are being conducted to identify, process, and create materials that are concurrently innocuous towards the environment and have superior properties. This book is a collection of such scientific articles that propagate novel ideas for the development of polymeric composite materials, which have application potential in numerous fields such as medicine, automobile, aviation, construction, etc. It also contains a pedagogical article that proposes some strategies to continue experimental research during pandemics. This book will provide readers a quick glance into recent developments regarding polymeric materials and will encourage them to propagate these research ideas further.


Book
Performance and Application of Novel Biocomposites
Author:
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Export citation

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Bookmark

Abstract

Amidst impending climate change and enhanced pollution levels around the globe, the need of the hour is to develop bio-based materials that are sustainable and possess comparable performance properties to their synthetic counterparts. In light of the aforementioned, numerous investigations are being conducted to identify, process, and create materials that are concurrently innocuous towards the environment and have superior properties. This book is a collection of such scientific articles that propagate novel ideas for the development of polymeric composite materials, which have application potential in numerous fields such as medicine, automobile, aviation, construction, etc. It also contains a pedagogical article that proposes some strategies to continue experimental research during pandemics. This book will provide readers a quick glance into recent developments regarding polymeric materials and will encourage them to propagate these research ideas further.


Book
Bio-Based and Biodegradable Plastics : From Passive Barrier to Active Packaging Behavior
Authors: --- ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Over the few coming decades, bio-based and biodegradable plastics produced from sustainable bioresources should essentially substitute the prevalent synthetic plastics produced from exhaustible hydrocarbon fossils. To the greatest extend, this innovative trend has to apply to the packaging manufacturing area and especially to food packaging implementation. To supply the rapid production increment of biodegradable plastics, there must be provided the effective development of scientific-technical potential that promotes the comprehensive exploration of their structural, functional, and dynamic characteristics. In this regard, the transition from passive barrier materials preventing water and oxygen transport as well as bacteria infiltration to active functional packaging that ensures gas diffusion selectivity, antiseptics' and other modifiers' release should be based on the thorough study of biopolymer crystallinity, morphology, diffusivity, controlled biodegradability and life cycle assessment. This Special Issue accumulates the papers of international teams that devoted to scientific and industrial bases providing the biodegradable material development in the barrier and active packaging as well as in agricultural applications. We hope that book will bring great interest to the experts in the area of sustainable biopolymers.


Book
Advances in Polyhydroxyalkanoate (PHA) Production, Volume 2
Author:
ISBN: 3039286412 3039286404 Year: 2020 Publisher: MDPI - Multidisciplinary Digital Publishing Institute

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Nowadays, we are witnessing highly dynamic research activities related to the intriguing field of biodegradable materials with plastic-like properties. These activities are stimulated by the strengthened public awareness of prevailing ecological issues connected to growing piles of plastic waste and increasing greenhouse gas emissions; this goes hand-in-hand with the ongoing depletion of fossil feedstocks, which are traditionally used to produce full carbon backbone polymers. Polyhydroxyalkanoate (PHA) biopolyesters, a family of plastic-like materials with versatile material properties, are increasing considered to be a future-oriented solution for diminishing these concerns. PHA production is based on renewable resources and occurs in a bio-mediated fashion through the action of living organisms. If accomplished in an optimized way, PHA production and the entire PHA lifecycle are embedded into nature´s closed cycles of carbon. Sustainable and efficient PHA production requires understanding and improvement of all the individual process steps. Holistic improvement of PHA production, applicable on an industrially relevant scale, calls for, inter alia, consolidated knowledge about the enzymatic and genetic particularities of PHA-accumulating organisms, an in-depth understanding of the kinetics of the bioprocess, the selection of appropriate inexpensive fermentation feedstocks, tailoring of PHA composition at the level of its monomeric constituents, optimized biotechnological engineering, and novel strategies for PHA recovery from biomass characterized by low energy and chemical requirements. This Special Issue represents a comprehensive compilation of articles in which these individual aspects have been addressed by globally recognized experts.

Keywords

Cupriavidus necator --- alginate --- tissue engineering --- PAT --- simulation --- terpolyester --- high cell density cultivation --- process simulation --- selective laser sintering --- gaseous substrates --- microaerophilic --- in-line monitoring --- Pseudomonas sp. --- additive manufacturing --- fed-batch --- terpolymer --- on-line --- bubble column bioreactor --- biopolymer --- fused deposition modeling --- biomaterials --- polyhydroxyalkanoate (PHA) --- Pseudomonas putida --- fed-batch fermentation --- blends --- upstream processing --- wound healing --- activated charcoal --- downstream processing --- Archaea --- polyhydroxyalkanoates processing --- film --- bioreactor --- medium-chain-length polyhydroxyalkanoate (mcl-PHA) --- poly(3-hydroxybutyrate-co-4-hydroxybutyrate) --- Ralstonia eutropha --- hydrolysate detoxification --- extremophiles --- Poly(3-hydroxybutyrate) --- process analytical technologies --- PHA composition --- COMSOL --- non-Newtonian fluid --- tequila bagasse --- biopolyester --- biosurfactants --- Haloferax --- PHA --- phenolic compounds --- polyhydroxybutyrate --- PHB --- in-line --- Pseudomonas --- haloarchaea --- plant oil --- PHA processing --- bioeconomy --- delivery system --- P(3HB-co-3HV-co-4HB) --- productivity --- electrospinning --- cyanobacteria --- waste streams --- polyhydroxyalkanoates --- oxygen transfer --- polyhydroxyalkanoate --- biomedical application --- photon density wave spectroscopy --- carbon dioxide --- salinity --- PDW --- rheology --- halophiles --- feedstocks --- high-cell-density fed-batch --- biomedicine --- process engineering --- bioprocess design --- viscosity --- computer-aided wet-spinning --- microorganism --- Cupriavidus malaysiensis --- poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHVB)


Book
Environmentally Friendly Polymers and Polymer Composites
Authors: --- --- --- ---
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Continuous research advances have been observed in the field of environmentally-friendly polymers and polymer composites due to the dependence of polymers on fossil fuels and the sustainability issues related to plastic wastes. This book compiles the most recent research works in biopolymers, their blends and composites, and the use of natural additives, such as vegetable oils and other renewable and waste-derived liquids, with their marked environmental efficiency devoted to developing novel sustainable materials. Therefore, Environmentally Friendly Polymers and Polymer Composites provides an overview to scientists of the potential of these environmentally friendly materials and helps engineers to apply these new materials for industrial purposes.

Keywords

Research & information: general --- PLA --- PCL --- TPS --- biopolymer blends --- mechanical properties --- compostable plastics --- green composites --- natural fillers --- poly(butylene succinate) (PBS) --- almond shell flour (ASF) --- poly (lactic acid) (PLA) --- poly(butylene succinate-co-adipate) (PBSA) --- binary blends --- shape memory behaviour --- polymer‒matrix composites (PMCs) --- thermomechanical --- electron microscopy --- compatibilizers --- poly(lactic acid) (PLA) --- natural fibre (NF) --- nano-hydroxyapatite (nHA) --- flammability --- crab shell --- chitin --- spherical microgels --- reverse micelle --- gelation --- chitosan (CS) --- anti-oxidant --- anti-apoptotic activity --- rotenone --- Parkinson’s disease (PD) --- composite materials --- hybrid resin --- natural reinforcement --- non-uniformities --- mechanical behavior --- antifungal activity --- dendrimer --- Origanum majorana L. essential oil --- Phytophthora infestans --- maleinized linseed oil MLO --- poly(lactic acid) --- diatomaceous earth --- biocomposites --- active containers --- polymer mixtures --- blends --- cashew nut shell liquid (CNSL) --- polypropylene --- high impact polystyrene --- compatibilization --- PHB --- PHBV --- rice husk --- biosustainability --- waste valorization --- bacterial cellulose --- natural rubber --- reinforcing --- biodegradable polymers --- Arboform --- epoxidized oil --- maleinized linseed oil --- toughness --- thermal stability --- pectin --- food packaging --- active compounds --- agro-waste residues --- circular economy --- graphene oxide --- size selection --- sodium alginate --- bio-based polymers --- biodegradable polyesters --- wood plastic composites --- natural additives and fillers --- composites characterization --- bioplastics manufacturing


Book
Environmentally Friendly Polymers and Polymer Composites
Authors: --- --- --- ---
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

Loading...
Export citation

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Bookmark

Abstract

Continuous research advances have been observed in the field of environmentally-friendly polymers and polymer composites due to the dependence of polymers on fossil fuels and the sustainability issues related to plastic wastes. This book compiles the most recent research works in biopolymers, their blends and composites, and the use of natural additives, such as vegetable oils and other renewable and waste-derived liquids, with their marked environmental efficiency devoted to developing novel sustainable materials. Therefore, Environmentally Friendly Polymers and Polymer Composites provides an overview to scientists of the potential of these environmentally friendly materials and helps engineers to apply these new materials for industrial purposes.

Keywords

Research & information: general --- PLA --- PCL --- TPS --- biopolymer blends --- mechanical properties --- compostable plastics --- green composites --- natural fillers --- poly(butylene succinate) (PBS) --- almond shell flour (ASF) --- poly (lactic acid) (PLA) --- poly(butylene succinate-co-adipate) (PBSA) --- binary blends --- shape memory behaviour --- polymer‒matrix composites (PMCs) --- thermomechanical --- electron microscopy --- compatibilizers --- poly(lactic acid) (PLA) --- natural fibre (NF) --- nano-hydroxyapatite (nHA) --- flammability --- crab shell --- chitin --- spherical microgels --- reverse micelle --- gelation --- chitosan (CS) --- anti-oxidant --- anti-apoptotic activity --- rotenone --- Parkinson’s disease (PD) --- composite materials --- hybrid resin --- natural reinforcement --- non-uniformities --- mechanical behavior --- antifungal activity --- dendrimer --- Origanum majorana L. essential oil --- Phytophthora infestans --- maleinized linseed oil MLO --- poly(lactic acid) --- diatomaceous earth --- biocomposites --- active containers --- polymer mixtures --- blends --- cashew nut shell liquid (CNSL) --- polypropylene --- high impact polystyrene --- compatibilization --- PHB --- PHBV --- rice husk --- biosustainability --- waste valorization --- bacterial cellulose --- natural rubber --- reinforcing --- biodegradable polymers --- Arboform --- epoxidized oil --- maleinized linseed oil --- toughness --- thermal stability --- pectin --- food packaging --- active compounds --- agro-waste residues --- circular economy --- graphene oxide --- size selection --- sodium alginate --- bio-based polymers --- biodegradable polyesters --- wood plastic composites --- natural additives and fillers --- composites characterization --- bioplastics manufacturing

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